Using precision coefficients on recurrence times and integrated currents to lower bound the average dissipation rate
Authors
Alberto Garilli, Diego Frezzato
Categories
Abstract
For continuous-time Markov jump processes on irreducible networks and time-independent rate constants, we employ a transition-based formalism to express the long-time precision of a single integrated current over an observable channel in terms of precisions of the recurrence times of the forward and backward jumps, and of an effective affinity that captures the thermodynamic driving on that channel. This leads to a general lower bound for the stationary entropy production rate that extends the well-known Thermodynamic Uncertainty Relation (TUR). Such an augmented TUR, which incorporates the statistics of the recurrences, proves to be tighter than the standard one far from equilibrium, and potentially offers new opportunities for the optimization and design of biological and chemical out-of-equilibrium systems at the nanoscale.
Using precision coefficients on recurrence times and integrated currents to lower bound the average dissipation rate
Categories
Abstract
For continuous-time Markov jump processes on irreducible networks and time-independent rate constants, we employ a transition-based formalism to express the long-time precision of a single integrated current over an observable channel in terms of precisions of the recurrence times of the forward and backward jumps, and of an effective affinity that captures the thermodynamic driving on that channel. This leads to a general lower bound for the stationary entropy production rate that extends the well-known Thermodynamic Uncertainty Relation (TUR). Such an augmented TUR, which incorporates the statistics of the recurrences, proves to be tighter than the standard one far from equilibrium, and potentially offers new opportunities for the optimization and design of biological and chemical out-of-equilibrium systems at the nanoscale.
Authors
Alberto Garilli, Diego Frezzato
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