Highly Anisotropic Charge Dynamics and Spectral Weight Redistribution in the Trilayer Nickelate La$_{4}$Ni$_{3}$O$_{10}$
Authors
Zhe Liu, Jie Li, Deyuan Hu, Bingke Ji, Haoran Zhang, Jiahao Hao, Yaomin Dai, Qing Li, Mengjun Ou, Bing Xu, Yi Lu, Meng Wang, Hai-Hu Wen
Categories
Abstract
We study the $ab$-plane and $c$-axis charge dynamics of La$_{4}$Ni$_{3}$O$_{10}$ using optical spectroscopy. While a pronounced Drude profile, i.e. metallic response, is observed in the $ab$-plane optical conductivity $σ_{1}^{ab}(ω)$, the $c$-axis optical spectra $σ_{1}^{c}(ω)$ exhibit semiconducting behavior. The zero-frequency extrapolation of the optical conductivity $σ_{1}(ω\rightarrow 0) \equiv 1/ρ_{\text{dc}}$ gives a resistivity anisotropy of $ρ_{c}/ρ_{ab} \simeq 366$ at 300 K for La$_{4}$Ni$_{3}$O$_{10}$, which is much larger than the values in iron-based superconductors but comparable to those in high-$T_{c}$ cuprates. The interband response is also highly anisotropic, showing salient orbital selectivity for light polarized in the $ab$ plane and along the $c$ axis. The interband-transition peaks in both $σ_{1}^{ab}(ω)$ and $σ_{1}^{c}(ω)$ are located at lower energies compared to density-functional-theory predictions, signifying considerable electronic correlations. By investigating the spectral weight transfer, we find that in the pristine phase, Coulomb correlations have a marked impact on the charge dynamics of \LNO, whereas in the density-wave state, a gap opens with the Ni-$d_{z^{2}}$ orbital being involved.
Highly Anisotropic Charge Dynamics and Spectral Weight Redistribution in the Trilayer Nickelate La$_{4}$Ni$_{3}$O$_{10}$
Categories
Abstract
We study the $ab$-plane and $c$-axis charge dynamics of La$_{4}$Ni$_{3}$O$_{10}$ using optical spectroscopy. While a pronounced Drude profile, i.e. metallic response, is observed in the $ab$-plane optical conductivity $σ_{1}^{ab}(ω)$, the $c$-axis optical spectra $σ_{1}^{c}(ω)$ exhibit semiconducting behavior. The zero-frequency extrapolation of the optical conductivity $σ_{1}(ω\rightarrow 0) \equiv 1/ρ_{\text{dc}}$ gives a resistivity anisotropy of $ρ_{c}/ρ_{ab} \simeq 366$ at 300 K for La$_{4}$Ni$_{3}$O$_{10}$, which is much larger than the values in iron-based superconductors but comparable to those in high-$T_{c}$ cuprates. The interband response is also highly anisotropic, showing salient orbital selectivity for light polarized in the $ab$ plane and along the $c$ axis. The interband-transition peaks in both $σ_{1}^{ab}(ω)$ and $σ_{1}^{c}(ω)$ are located at lower energies compared to density-functional-theory predictions, signifying considerable electronic correlations. By investigating the spectral weight transfer, we find that in the pristine phase, Coulomb correlations have a marked impact on the charge dynamics of \LNO, whereas in the density-wave state, a gap opens with the Ni-$d_{z^{2}}$ orbital being involved.
Authors
Zhe Liu, Jie Li, Deyuan Hu et al. (+10 more)
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